Naphthenic Acid Corrosion Testing

Naphthenic Acid Corrosion Testing

 

Several set-ups can be used to test crude oils and cuts for naphthenic acid corrosion at high shear stresses (hundreds Pa). The optimal set-up to be used requires that:

 

  • The TAN does not decrease during the test.
  • The corrosion inhibitor if used in the test does not decompose and its concentration does not decrease during the test.
  • Several specimens can be tested at the same time.

Comparison of Testing Methods for Oil Testing

 

Set-Up Max # of specimens Amount of Test Fluid (liters) Once-Through Flow Re-circulating Fluid TAN Decrease Inhibitor Decomposition
Rotating cage 8 or more* 1 to 4 No Yes Yes Yes
Rotating cage with stopping and fluid replenishment every day 8 or more* 12 (4-day run) No No No No
Flow loop with continuous replenishment of rotating cage 8 or more* 15 (4-day run) Yes No No No

 

The replenished autoclave and the flow loop look like the best methods for testing high temperature corrosion inhibitors for naphthenic corrosion.